# file: itn_F12_All.dat # # Atmospheric measurements of CCl2F2 (CFC-12, Chlorofluorocarbon-12, F12) # # Measurements are from the NOAA/ESRL/GMD/HATS flask program # (http://www.esrl.noaa.gov/gmd/hats/flask/flasks.html). # Instrument ID: Otto # # Location: ITN -- Grifton, North Carolina -- 35.37 N, 77.39 W, 8 m Elev. # See http://www.esrl.noaa.gov/gmd/dv/site/site_table.html#hats_flask for # more information about flask sampling sites. # # The data reported are from samples collected approximately once per week in # matching, concurrent, flask pairs and later analyzed on a gas chromatograph # with electron capture detection (GC-ECD) located in Boulder, Colorado, USA. # This system uses two standard reference gases for calibration and has been # in operation since very early in 1995. # # These data represent mean estimates from pairs of concurrently-collected # flask samples based on several injections from each flask. Mean estimates # are derived for each individual flask, then the flask estimates are combined # into a single estimate for the pair. Ideally, each concentration is estimated # three different ways using three simple calibration curves. A two-point # calibration is derived from nearby responses to both reference gases # considered in unison, and separate one-point calibrations are derived from # nearby responses to each reference gas considered in isolation from the # other. These estimates are then reconciled in accordance with the method # outlined at # # ftp://aftp.cmdl.noaa.gov/data/hats/doc/HATSflaskECDanalysis.docx # # A series of seven binary QC flag fields is included with each entry. In order # from left to right, a 1 signifies that 1) a single reference gas was used for # calibration, 2) one or more sample injections occurred at subambient flask # pressure (raising the risk of contamination), 3) the precision of the # estimate is worse than 2.5% of the mean, 4) the estimate has been flagged -- # either by a loess-based statistical outlier algorithm, or, on occasion, # selectively -- as "suspect", 5) the estimate is based on a single flask # sample with a missing paired partner, 6) the estimates from the individual # flask partners disagree by more than twice their summed precisions. The # seventh and final flag is turned on whenever one of flags 4, 5 or 6 is # thrown. This is to conveniently mark samples that are excluded from the # computation of monthly mean values presented in the companion file named # "itn_F12_MM.dat". Flags 1, 2 and 3 are considered purely descriptive in # nature, serving only to raise suspicion of a sample. Flag 4 promotes any # suspicion to exclusionary status. The algorithm used for setting flag 4 is # applied only to baseline (i.e. coastal, high-altitude, or otherwise remote) # sites. Samples from continental sites known to have nearby urban influences # (e.g. HFM, ITN, and LEF) are flagged as suspect only when obvious # chromatography issues were present during the analysis. This elevates the # risk of sample over-exclusion (i.e. false positives occurring in flag 4 and # hence also in flag 7) among the baseline sites, while for the continental, # urban-influenced sites there is a greater risk of sample under-exclusion. # # PIs: Dr. James W. Elkins, Dr. Bradley D. Hall, # Debra J. Mondeel, J. David Nance # # National Oceanic and Atmospheric Administration (NOAA) # Earth System Research Laboratory (ESRL) # 325 Broadway, R/GMD1 # Boulder, CO 80305-3328 # # Email: James.W.Elkins@noaa.gov; Bradley.Hall@noaa.gov # Phone: (303) 497-6224 (303) 497-7011 # # Email: Debra.J.Mondeel@noaa.gov; David.Nance@noaa.gov # Phone: (303) 497-6013 (303) 497-7002 # # Fax: (303) 497-6290 # # Data use policy: # If you use this data in a publication or report, we would appreciate that you # contact the principal investigators (PIs) first and discuss your interests. # The PIs can discuss the quality of the data and any potential problems with # its analysis. Please contact the PIs for more information. The data should # be cited in presentations or publications along the following lines: CFC-12 # data from the NOAA/ESRL halocarbons flask program. # # Calibration scale: NOAA 2008 # See http://www.esrl.noaa.gov/gmd/ccl/scales.html for more information about # calibration scales. # # Units: ppt # # Missing value: "nan" # # Data Columns: # yr Year # mon Month # day Day of the Month # hour Hour of the Day # min Minute of the Hour # m Mean flask-pair concentration of F12 in ppt # sd Standard deviation # pid Flask-pair ID # ftype Type of flasks in pair # U: unknown # S: stainless steel # G: glass # B: both (i.e. one of each) # flag1 0: normal (this also applies to all flags that follow) # 1: a single reference gas was used for calibration # flag2 1: one or more sample injections occurred at subambient pressure # flag3 1: precision > 2.5% of estimated concentration # flag4 1: marked suspect by a loess-based statistical outlier algorithm # flag5 1: single flask with missing paired partner # flag6 1: paired partners disagree by more than twice their summed # precisions # flag7 1: sample excluded from monthly mean computations ("itn_F12_MM.dat") # F12ottoITNyr F12ottoITNmon F12ottoITNday F12ottoITNhour F12ottoITNmin F12ottoITNm F12ottoITNsd F12ottoITNpid F12ottoITNftype F12ottoITNflag1 F12ottoITNflag2 F12ottoITNflag3 F12ottoITNflag4 F12ottoITNflag5 F12ottoITNflag6 F12ottoITNflag7 1995 08 16 16 19 550.159 3.409 00239 S 0 0 0 0 0 0 0 1995 10 25 15 00 540.220 2.406 00295 S 1 0 0 0 0 0 0 1995 11 22 16 12 536.792 1.244 00344 S 1 0 0 0 0 0 0 1996 01 03 18 17 550.887 2.062 00372 S 1 0 0 0 0 0 0 1996 01 17 17 50 535.294 1.118 00384 S 1 0 0 0 0 0 0 1996 02 21 16 19 545.263 1.833 00413 S 1 0 0 0 0 0 0 1996 03 27 15 25 538.465 1.073 00451 S 1 0 0 0 1 0 1 1996 04 10 14 35 541.312 0.978 00462 S 1 0 0 0 0 0 0 1996 05 01 15 14 541.315 0.881 00478 S 1 0 0 0 0 0 0 1996 05 15 16 44 539.803 1.383 00494 S 1 0 0 0 0 0 0 1996 05 29 16 55 556.853 1.021 00502 S 1 0 0 0 0 0 0 1996 06 12 17 15 539.504 1.767 00521 S 1 0 0 0 0 0 0 1996 06 26 16 25 543.070 1.340 00537 S 1 0 0 0 0 0 0 1996 07 10 16 25 547.762 1.056 00552 S 1 0 0 0 0 0 0 1996 07 24 15 55 542.005 1.630 00563 S 1 0 0 0 0 0 0 1996 08 07 16 25 558.291 2.622 00567 S 1 0 0 0 0 0 0 1996 08 21 15 30 555.334 0.722 00592 S 1 0 0 0 0 0 0 1996 09 04 15 30 535.985 0.845 00606 S 1 0 0 0 0 0 0 1996 09 18 15 50 547.707 0.818 00618 S 1 0 0 0 0 0 0 1996 10 23 16 25 543.979 1.517 00648 S 1 0 0 0 0 0 0 1996 11 06 17 14 542.081 1.084 00658 S 1 0 0 0 0 0 0 1996 11 27 16 54 541.445 0.783 00689 S 1 0 0 0 0 0 0 1996 12 11 16 44 542.761 1.111 00698 S 1 0 0 0 0 0 0 1997 01 02 16 55 540.420 1.335 00728 S 1 0 0 0 0 0 0 1997 01 22 16 44 540.412 0.980 00738 S 1 0 0 0 0 0 0 1997 02 05 16 25 545.805 0.570 00759 S 1 0 0 0 0 0 0 1997 02 19 16 15 542.168 1.274 00770 S 1 0 0 0 0 0 0 1997 03 26 17 15 539.686 1.875 00802 S 1 0 0 0 0 0 0 1997 04 09 16 50 542.681 1.646 00815 S 1 0 0 0 0 0 0 1997 04 23 15 24 540.441 1.594 00822 S 1 0 0 0 0 0 0 1997 07 02 16 20 538.227 1.321 00884 S 1 0 0 0 0 0 0 1997 07 16 16 25 550.591 0.698 00897 S 1 0 0 0 0 0 0 1997 08 13 16 04 549.265 0.697 00935 S 1 0 0 0 0 0 0 1997 08 27 16 09 545.286 1.341 00940 S 1 0 0 0 0 0 0 1997 09 17 16 44 549.852 1.048 00954 S 1 0 0 0 0 0 0 1997 10 08 15 49 556.601 1.306 00971 S 1 0 0 0 0 0 0 1997 10 29 16 34 565.118 1.174 00984 S 1 0 0 0 0 0 0 1997 11 19 16 40 554.986 0.851 01005 S 1 0 0 0 0 0 0 1997 12 10 16 55 541.749 1.441 01047 S 1 0 0 0 0 0 0 1998 01 07 17 00 539.404 1.656 01061 S 1 0 0 0 0 0 0 1998 01 28 16 49 540.743 2.022 01079 S 1 0 0 0 0 0 0 1998 02 18 16 44 543.662 1.030 01103 S 1 0 0 0 0 0 0 1998 03 11 17 15 542.749 1.290 01118 S 1 0 0 0 0 0 0 1998 04 01 16 55 540.622 2.490 01136 S 1 0 0 0 0 0 0 1998 04 15 14 49 545.338 1.044 01153 S 1 0 0 0 0 0 0 1998 05 27 15 44 560.940 0.923 01191 S 1 0 0 0 0 0 0 1998 06 24 15 19 551.026 1.221 01221 S 1 0 0 0 0 0 0 1998 07 01 15 45 553.897 0.464 01224 S 1 0 0 0 0 0 0 1998 08 19 15 44 555.486 0.551 01284 S 1 0 0 0 0 0 0 1998 09 15 16 14 548.740 1.096 01308 S 0 0 0 0 0 0 0 1998 10 07 16 05 545.690 0.715 01334 S 0 0 0 0 0 0 0 1998 10 28 16 40 547.911 1.160 01358 S 0 0 0 0 0 0 0 1998 11 25 15 14 547.239 1.280 01397 S 0 0 0 0 0 0 0 1998 12 09 17 15 550.174 1.459 01428 S 0 0 0 0 0 0 0 1998 12 30 16 55 544.010 1.320 01436 S 0 0 0 0 0 0 0 1999 01 27 15 20 548.163 1.398 01459 S 0 0 0 0 0 0 0 1999 02 10 16 34 544.914 1.109 01483 S 0 0 0 0 0 0 0 1999 03 03 16 24 544.827 1.358 01522 S 0 0 0 0 0 0 0 1999 03 24 15 59 545.594 2.237 01529 S 0 0 0 0 0 0 0 1999 04 21 15 25 548.287 1.200 01553 S 0 0 0 0 0 0 0 1999 05 05 15 05 544.243 1.365 01575 S 0 0 0 0 0 0 0 1999 05 12 15 34 543.182 1.578 01587 S 0 0 0 0 0 0 0 1999 05 26 14 34 544.218 1.295 01599 S 0 0 0 0 0 0 0 1999 06 02 15 19 544.842 0.806 01608 S 0 0 0 0 0 0 0 1999 06 09 14 39 555.123 1.110 01618 S 0 0 0 0 0 0 0