file: RITS_global_N2O.txt Nitrous Oxide (N2O) hemispheric and global monthly means from the NOAA/ESRL halocarbons program. The following data is a combined data set from two or more measurement programs. Weighted averages of monthly mean data are combined, interpolated, and smoothed for each sampling location. Hemispheric and global means are estimated by cosine weighting by latitude. (PIs) Dr. James W. Elkins, Geoffrey S. Dutton, Dr. Bradley D. Hall National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory (ESRL) 325 Broadway, R/GMD1 Boulder, CO 80305-3328 Email: James.W.Elkins@noaa.gov; Bradley.Hall@noaa.gov; Geoff.Dutton@noaa.gov Phone: (303) 497-6224 (303) 497-7011 (303) 497-6086 Fax: (303) 497-6290 This work was funded in part by the Atmospheric Chemistry Project of NOAA's Climate and Global Change Program. Data use policy: These data are made freely available to the public and the scientific community in the belief that their wide dissemination will lead to greater understanding and new scientific insights. The availability of these data does not constitute publication of the data. NOAA relies on the ethics and integrity of the user to assure that ESRL receives fair credit for their work. If the data are obtained for potential use in a publication or presentation, ESRL should be informed at the outset of the nature of this work. If the ESRL data are essential to the work, or if an important result or conclusion depends on the ESRL data, co-authorship may be appropriate. This should be discussed at an early stage in the work. Manuscripts using the ESRL data should be sent to ESRL for review before they are submitted for publication so we can insure that the quality and limitations of the data are accurately represented. The PIs can discuss the quality of the data and any potential problems with its analysis. Recent data (less than 1.5 years) are considered preliminary. Please contact the PIs for more information. The data should be cited in presentations or publications as the flowing: RITS Nitrous Oxide data from the NOAA/ESRL halocarbons program. Calibration scale used: NOAA 2006 More information about the calibration scale can be found at: http://www.esrl.noaa.gov/gmd/ccl/index.html Global monthly data are provided in parts-per-billion, ppb. NOAA/GMD Halocarbon Network, See (http://www.esrl.noaa.gov/gmd/dv/site/site_table.html#hats_flask) more information on current halocarbon sampling sites. alt=Alert, North West Territories, Canada (82.5N, 62.3W) (Atmospheric Environment Service Site); brw=Pt. Barrow, Alaska, USA (71.3N, 156.6W) (flask and in insitu); lef=Wisconsin, USA, (45.6N, 90.2W) (WLEF Television tower); nwr=Niwot Ridge, Colorado, USA (40.052N, 105.585W) (University of Colorado site)(flask and in insitu); kum=Cape Kumukahi, Hawaii, USA (19.5N, 154.8W); mlo=Mauna Loa, Hawaii, USA (19.5N, 155.6W)(flask and in insitu); smo=Cape Matatula, American Samoa (14.3S, 170.6W)(flask and in insitu); cgo=Cape Grim, Tasmania, Australia (40.7S, 144.8E) (CSIRO/Australia site); psa=Palmer Station, Antarctica (64.6S, 64.0W) -GLASS FLASKS ONLY; spo=South Pole (90S)(flask and in insitu); hfm=Massachusetts, USA (42.5N, 72.2W, 340m) (Harvard University site); mhd=Mace Head, Ireland (53N, 10W); thd=Trinidad Head, USA (41N, 124W, 120m); tdf=Tierra del Fuego, Ushauia, Argentina (54.8S, 68.3W, 10); sum=Summit, Greenland (72.6N, 38.4W, 3210m)-GLASS FLASKS ONLY (flask and in insitu); See (http://www.esrl.noaa.gov/gmd/obop/) for station statistics and personnel. The last column of data is a five digit binary number that lists the measurement projects used in calculating the assimilated global mean. A number 1 indicates data from the corresponding project was uses. The binary number is arranged from left to right: oldGC, RITS, otto, CATS, MS oldGC = Original flask program started in 1977 at NOAA baseline observatories, expanded to 7 sites. RITS = In-situ program started in 1987 at 4 stations (NWR added in 1990). otto = New flask analysis GC installed in 1995, currently 11 sample sites. CATS = New in-situ GCs installed from 1998-2000 at 5 stations. Summit, Greenland added in 2007. MS = Flasks analyzed via mass spectrometry. nan = not a number or no data, and space(s) is the delimiter. The hemispheric and global mean error estimates are calculated using 1-standard deviation errors assigned to the individual programs plus a systematic errors due to smoothing and interpolating. RITS_N2O_YYYY RITS_N2O_MM RITS_NH_N2O RITS_NH_N2O_sd RITS_SH_N2O RITS_SH_N2O_sd RITS_Global_N2O RITS_Global_N2O_sd RITS_N2O_Programs 1987 1 nan nan nan nan nan nan 01000 1987 2 nan nan nan nan nan nan 01000 1987 3 nan nan nan nan nan nan 01000 1987 4 nan nan nan nan nan nan 01000 1987 5 nan nan nan nan nan nan 01000 1987 6 nan nan nan nan nan nan 01000 1987 7 nan nan nan nan nan nan 01000 1987 8 nan nan nan nan nan nan 01000 1987 9 nan nan nan nan nan nan 01000 1987 10 306.850 0.395 nan nan nan nan 01000 1987 11 306.919 0.375 nan nan nan nan 01000 1987 12 307.014 0.628 nan nan nan nan 01000 1988 1 307.087 0.754 nan nan nan nan 01000 1988 2 307.077 0.553 nan nan nan nan 01000 1988 3 307.062 0.401 nan nan nan nan 01000 1988 4 307.085 0.363 306.053 0.427 306.569 0.560 01000 1988 5 307.084 0.421 305.954 0.318 306.519 0.528 01000 1988 6 307.068 0.501 305.932 0.334 306.500 0.602 01000 1988 7 307.059 0.367 306.001 0.732 306.530 0.819 01000 1988 8 307.057 0.382 306.111 0.629 306.584 0.736 01000 1988 9 307.123 0.315 306.259 0.491 306.691 0.584 01000 1988 10 307.277 0.251 306.513 0.291 306.895 0.385 01000 1988 11 307.455 0.277 306.807 0.364 307.131 0.458 01000 1988 12 307.620 0.334 307.024 0.249 307.322 0.417 01000 1989 1 307.757 0.325 307.173 0.391 307.465 0.508 01000 1989 2 307.791 0.334 307.266 0.342 307.529 0.479 01000 1989 3 307.649 0.500 307.279 0.237 307.464 0.553 01000 1989 4 307.462 0.819 307.269 0.290 307.366 0.869 01000 1989 5 307.467 0.278 307.284 0.378 307.376 0.469 01000 1989 6 307.660 0.186 307.307 0.284 307.484 0.340 01000 1989 7 307.870 0.240 307.357 0.244 307.614 0.342 01000 1989 8 308.019 0.317 307.464 0.253 307.742 0.406 01000 1989 9 308.148 0.353 307.619 0.248 307.883 0.432 01000 1989 10 308.284 0.342 307.810 0.229 308.047 0.412 01000 1989 11 308.406 0.284 308.010 0.430 308.208 0.515 01000 1989 12 308.514 0.323 308.147 0.491 308.330 0.587 01000 1990 1 308.606 0.326 308.189 0.336 308.398 0.468 01000 1990 2 308.642 0.290 308.201 0.283 308.422 0.405 01000 1990 3 308.638 0.491 308.200 0.385 308.419 0.624 01000 1990 4 309.011 0.369 308.161 0.295 308.586 0.472 01000 1990 5 308.867 0.376 308.137 0.288 308.502 0.474 01000 1990 6 308.720 0.455 308.174 0.268 308.447 0.528 01000 1990 7 308.649 0.578 308.258 0.344 308.453 0.673 01000 1990 8 308.709 0.403 308.369 0.450 308.539 0.604 01000 1990 9 308.840 0.471 308.475 0.804 308.658 0.932 01000 1990 10 308.997 0.364 308.571 1.385 308.784 1.432 01000 1990 11 309.175 0.379 308.699 1.056 308.937 1.122 01000 1990 12 309.343 0.292 308.900 0.507 309.121 0.585 01000 1991 1 309.467 0.279 309.138 0.424 309.302 0.508 01000 1991 2 309.533 0.270 309.254 0.584 309.394 0.643 01000 1991 3 309.548 0.365 309.149 0.803 309.349 0.882 01000 1991 4 309.492 0.405 308.998 1.454 309.245 1.509 01000 1991 5 309.315 0.304 308.985 0.472 309.150 0.562 01000 1991 6 309.089 0.322 309.025 0.371 309.057 0.491 01000 1991 7 308.969 0.284 309.047 0.414 309.008 0.502 01000 1991 8 309.014 0.225 309.136 0.327 309.075 0.397 01000 1991 9 309.191 0.267 309.271 0.409 309.231 0.488 01000 1991 10 309.435 0.346 309.357 0.309 309.396 0.464 01000 1991 11 309.683 0.354 309.393 0.247 309.538 0.432 01000 1991 12 309.901 0.354 309.452 0.301 309.676 0.464 01000 1992 1 310.053 0.415 309.567 0.294 309.810 0.508 01000 1992 2 310.132 0.325 309.658 0.683 309.895 0.756 01000 1992 3 310.147 0.359 309.643 0.237 309.895 0.430 01000 1992 4 310.104 0.301 309.561 0.238 309.833 0.384 01000 1992 5 310.058 0.346 309.487 0.375 309.773 0.510 01000 1992 6 310.046 0.271 309.472 0.287 309.759 0.395 01000 1992 7 310.043 0.291 309.546 0.209 309.794 0.358 01000 1992 8 310.033 0.282 309.655 0.257 309.844 0.382 01000 1992 9 310.050 0.306 309.719 0.186 309.884 0.358 01000 1992 10 310.126 0.233 309.743 0.220 309.934 0.321 01000 1992 11 310.220 0.314 309.807 0.314 310.013 0.444 01000 1992 12 310.292 0.379 309.942 0.389 310.117 0.543 01000 1993 1 310.370 0.380 310.107 0.305 310.238 0.487 01000 1993 2 310.459 0.331 310.253 0.433 310.356 0.545 01000 1993 3 310.512 0.311 310.285 0.441 310.399 0.540 01000 1993 4 310.492 0.323 310.127 0.420 310.309 0.530 01000 1993 5 310.408 0.256 309.917 0.532 310.162 0.591 01000 1993 6 310.314 0.339 309.864 0.276 310.089 0.437 01000 1993 7 310.269 0.326 309.972 0.302 310.121 0.444 01000 1993 8 310.308 0.259 310.101 0.345 310.204 0.432 01000 1993 9 310.449 0.396 310.155 0.321 310.302 0.509 01000 1993 10 310.644 0.406 310.174 0.373 310.409 0.551 01000 1993 11 310.804 0.432 310.230 0.307 310.517 0.530 01000 1993 12 310.910 0.313 310.271 0.452 310.591 0.550 01000 1994 1 310.990 0.308 310.262 0.384 310.626 0.492 01000 1994 2 311.064 0.272 310.287 0.290 310.675 0.398 01000 1994 3 311.151 0.221 310.384 0.279 310.767 0.356 01000 1994 4 311.221 0.314 310.496 0.318 310.858 0.447 01000 1994 5 311.253 0.407 310.600 0.345 310.926 0.534 01000 1994 6 311.283 0.332 310.679 0.335 310.981 0.472 01000 1994 7 311.319 0.455 310.698 0.426 311.008 0.623 01000 1994 8 311.300 0.600 310.733 0.685 311.017 0.911 01000 1994 9 311.222 0.536 310.895 0.287 311.059 0.608 01000 1994 10 311.202 0.542 311.155 0.395 311.178 0.670 01000 1994 11 311.296 0.705 311.451 0.673 311.373 0.975 01000 1994 12 311.410 0.976 311.674 0.985 311.542 1.387 01000 1995 1 311.469 0.602 311.630 0.855 311.550 1.046 01000 1995 2 311.466 0.418 311.327 0.616 311.396 0.745 01000 1995 3 311.408 0.549 310.995 0.600 311.201 0.814 01000 1995 4 311.320 0.754 310.772 0.437 311.046 0.871 01000 1995 5 311.226 0.798 310.620 0.462 310.923 0.922 01000 1995 6 311.133 0.441 310.490 0.319 310.812 0.544 01000 1995 7 311.062 0.379 310.407 0.207 310.735 0.432 01000 1995 8 311.015 0.341 310.415 0.281 310.715 0.441 01000 1995 9 311.041 0.363 310.505 0.282 310.773 0.460 01000 1995 10 311.247 0.481 310.641 0.350 310.944 0.595 01000 1995 11 311.520 0.667 310.867 0.327 311.194 0.743 01000 1995 12 311.619 0.467 311.212 0.433 311.416 0.637 01000 1996 1 311.651 0.677 311.446 0.976 311.548 1.188 01000 1996 2 311.849 0.625 311.356 0.506 311.603 0.804 01000 1996 3 312.118 0.561 311.102 0.379 311.610 0.677 01000 1996 4 312.329 1.231 310.917 0.475 311.623 1.319 01000 1996 5 312.477 1.406 310.865 0.360 311.671 1.452 01000 1996 6 312.446 1.634 310.912 0.326 311.679 1.666 01000 1996 7 312.289 1.811 310.990 0.329 311.639 1.840 01000 1996 8 312.271 1.005 311.071 0.488 311.671 1.117 01000 1996 9 312.411 0.718 311.172 0.474 311.792 0.860 01000 1996 10 312.565 0.474 311.319 0.626 311.942 0.785 01000 1996 11 312.708 0.490 311.497 0.447 312.102 0.663 01000 1996 12 312.856 0.934 311.646 0.364 312.251 1.002 01000 1997 1 312.986 0.776 311.758 0.502 312.372 0.925 01000 1997 2 313.003 0.506 311.852 0.495 312.428 0.708 01000 1997 3 312.855 0.689 311.870 0.448 312.363 0.822 01000 1997 4 312.712 0.838 311.774 0.478 312.243 0.965 01000 1997 5 312.760 0.471 311.657 0.666 312.208 0.816 01000 1997 6 312.939 0.642 311.646 0.708 312.292 0.956 01000 1997 7 313.096 0.361 311.731 0.628 312.413 0.724 01000 1997 8 313.188 0.369 311.828 0.445 312.508 0.578 01000 1997 9 313.270 0.318 311.927 0.426 312.598 0.531 01000 1997 10 313.394 0.508 311.997 0.478 312.695 0.698 01000 1997 11 313.541 0.697 311.981 0.396 312.761 0.802 01000 1997 12 313.696 0.529 311.958 0.560 312.827 0.770 01000 1998 1 313.892 0.480 312.020 0.963 312.956 1.076 01000 1998 2 314.095 0.319 312.119 0.661 313.107 0.733 01000 1998 3 314.185 0.497 312.188 0.527 313.186 0.724 01000 1998 4 314.156 0.533 312.230 0.557 313.193 0.771 01000 1998 5 314.170 0.503 312.258 0.443 313.214 0.671 01000 1998 6 314.305 0.515 312.268 0.495 313.287 0.714 01000 1998 7 314.498 0.376 312.306 0.766 313.402 0.853 01000 1998 8 314.688 0.428 312.438 0.695 313.563 0.816 01000 1998 9 314.876 0.545 312.639 0.395 313.758 0.673 01000 1998 10 315.042 0.674 312.871 0.437 313.957 0.804 01000 1998 11 315.154 0.494 313.169 0.518 314.161 0.716 01000 1998 12 315.215 0.772 313.502 0.727 314.358 1.061 01000 1999 1 315.257 0.659 313.709 0.761 314.483 1.007 01000 1999 2 315.238 0.607 313.691 0.561 314.464 0.827 01000 1999 3 315.286 1.190 313.548 0.659 314.417 1.361 01000 1999 4 315.354 0.970 313.418 0.603 314.386 1.142 01000 1999 5 315.356 0.747 313.383 0.622 314.370 0.972 01000 1999 6 315.231 0.641 313.487 0.586 314.359 0.869 01000 1999 7 315.052 0.622 313.650 0.583 314.351 0.853 01000 1999 8 314.969 0.940 313.784 0.530 314.376 1.079 01000 1999 9 315.020 0.806 313.946 0.541 314.483 0.971 01000 1999 10 315.164 0.512 314.185 0.558 314.675 0.757 01000 1999 11 315.407 0.845 314.437 0.559 314.922 1.013 01000 1999 12 315.711 0.900 314.634 0.512 315.173 1.035 01000 2000 1 315.965 0.722 314.763 0.612 315.364 0.946 01000 2000 2 316.114 0.909 314.818 0.757 315.466 1.183 01000 2000 3 316.201 0.862 314.821 0.861 315.511 1.219 01000 2000 4 316.225 0.468 314.676 0.889 315.451 1.005 01000 2000 5 nan nan 314.914 1.185 nan nan 01000