OAX_F22.TXT =========== HCFC-22 28-Jun-95 16:38:17 J.M. Lobert, T.J. Baring, J.H. Butler, S.A. Montzka, R.C. Myers, and J.W. Elkins 1992 NOAA/CMDL, 325 Broadway R/E/CG1, Boulder, CO 80303 Ocean/Air Exchange of Trace Compounds 1992: Oceanic Measurements of HCFC-22, CFC-11, CFC-12, CFC-113, CH3CCl3, CCl4, and N2O in marine air and surface waters of the West Pacific Ocean (03. August to 21 October 1992). NOAA Technical Memorandum ERL CMDL-x. Available through authors or National Technical Information Service (NTIS), 5285 Royal Port Road, Springfield, VA 22161, USA ------------------------------------------------------------------------------- UNITS: ****** * "A" stands for AIR, "E" stands for Equilibrator (surface water), "SA" is the saturation anomaly, "NetSA" is the NET saturation anomaly (corrected for physical behavior). * all latitudes are in degrees, negative if south of the equator. * all mixing ratios are in parts per trillion (ppt), except for nitrous oxide which is in parts per billion (ppb) * all times are in Julian Day of the year 1992. * all saturation anomalies are in percent. * Station data reflect the stations of Niwot Ridge, CO (40.1°), Mauna Loa (19.5°), American Samoa (-14.2°). ------------------------------------------------------------------------------- HCFC-22 no data north of 24 degrees N were obtained for HCFC-22. Air Equilibrator Saturation anomalies Flask data F22_A_lat F22_A_mr F22_E_lat F22_E_mr F22_SA_lat F22_SA F22_NetSA_lat F22_NetSA Flask_Lat_A Flask_DOY_A Flask_F22_A Flask_Lat_E Flask_DOY_E Flask_F22_E 24.388 106.495 24.320 115.302 24.388 8.270 24.388 7.532 52.850 236.567 52.717 236.599 24.184 112.517 24.116 111.564 24.184 -0.847 24.184 -2.161 50.800 238.240 50.667 238.260 24.082 114.433 23.197 110.983 24.082 -3.014 24.082 -2.961 46.367 241.102 46.267 241.124 15.684 112.807 17.176 111.158 23.491 -1.981 23.491 -3.248 40.987 246.344 110.8 40.895 246.368 15.324 112.286 23.567 102.186 26.757 8.569 26.757 8.569 37.495 249.668 108.6 36.466 249.693 18.662 109.550 23.791 112.235 27.115 0.086 27.115 0.086 34.166 251.313 109.9 34.076 251.336 111.3 23.491 104.251 23.938 104.640 27.470 2.050 27.470 2.050 31.280 253.734 110.0 31.160 253.769 111.8 24.065 108.038 26.209 103.534 28.018 4.106 28.018 4.106 28.015 255.703 102.5 27.696 255.767 112.3 26.757 104.784 26.342 102.565 28.039 3.318 28.039 3.318 25.761 256.167 104.7 25.559 256.207 27.115 107.304 26.685 111.282 28.048 -4.036 28.048 -4.036 23.800 256.582 103.4 23.862 256.566 27.470 107.567 26.829 113.763 27.804 -5.325 27.804 -6.690 17.162 282.297 17.098 282.317 111.3 28.018 107.735 27.329 107.397 27.685 6.788 27.685 5.050 20.960 257.201 102.6 20.805 257.233 108.5 28.024 112.632 27.541 109.772 27.085 -1.296 27.085 -1.296 12.780 283.822 12.658 283.850 109.7 28.032 109.177 28.015 104.142 26.810 -2.659 26.810 -2.659 7.026 285.783 105.4 6.905 285.808 28.039 101.896 28.021 112.159 26.598 1.382 26.598 1.382 16.408 258.115 16.242 258.146 28.048 109.842 28.043 105.276 26.454 -0.502 26.454 -0.502 14.865 258.418 100.2 14.773 258.437 27.925 110.149 28.045 105.409 25.585 -2.588 25.585 -4.544 4.933 286.379 5.003 286.360 27.804 110.455 27.745 104.574 25.109 -1.342 24.973 1.722 3.486 286.833 101.7 3.289 286.871 106.0 27.685 107.146 27.566 114.419 24.973 1.722 24.644 -3.465 10.236 284.698 109.6 10.161 284.714 102.3 27.085 110.271 27.448 111.259 24.644 -3.465 24.504 2.925 8.310 285.313 103.3 8.217 285.332 26.810 108.064 27.021 108.841 24.504 2.925 24.367 3.855 1.585 287.537 103.3 1.654 287.519 26.598 107.563 26.880 99.838 24.367 3.855 24.159 3.610 -0.035 288.753 -0.189 288.787 26.454 109.406 26.669 105.190 24.159 3.610 24.022 -1.614 -2.440 289.919 -2.633 289.948 25.585 108.366 26.526 109.050 24.022 -1.614 21.922 -2.632 -6.053 291.437 -5.920 291.412 25.441 102.858 26.381 108.857 21.922 -2.190 21.707 4.214 -11.031 292.569 -11.104 292.584 25.308 101.312 25.731 107.870 21.707 3.619 21.352 4.183 -15.969 293.583 98.1 -16.059 293.600 25.109 111.651 25.513 105.561 21.352 3.952 21.212 -7.357 -20.315 294.410 98.5 -20.407 294.430 98.4 24.973 108.288 24.769 110.153 21.212 -6.981 21.072 7.340 24.644 110.690 24.574 106.854 21.072 6.067 20.856 -2.094 24.504 105.753 24.435 108.847 20.856 -1.543 20.721 -9.104 24.367 105.050 24.091 109.099 20.721 -8.623 20.516 1.191 24.159 105.298 21.776 109.757 20.516 0.818 19.856 2.411 24.022 111.558 21.635 109.003 20.251 -1.832 19.725 -2.278 21.922 112.215 21.488 109.675 19.856 1.989 19.527 -3.377 21.707 105.196 21.279 112.947 19.725 -2.086 19.394 -7.874 21.352 108.653 21.141 101.624 19.527 -3.725 19.191 -8.122 21.212 109.251 20.926 107.160 19.394 -8.663 18.698 3.463 21.072 101.030 20.791 108.593 19.191 -7.177 18.556 3.055 20.856 110.295 20.649 99.893 18.698 4.155 18.342 4.210 20.721 109.320 20.445 106.673 18.556 3.591 18.201 0.876 20.516 105.807 19.791 101.524 18.342 4.659 17.378 3.232 20.379 110.048 19.594 107.324 18.201 0.737 17.241 -5.452 20.251 103.419 19.461 104.820 17.378 3.921 17.035 5.039 19.856 99.544 19.327 104.082 17.241 -4.981 16.897 7.078 19.725 109.611 19.122 103.776 17.035 5.071 16.415 -6.093 19.527 108.876 18.769 107.406 16.897 7.713 16.211 -3.271 19.394 113.954 18.485 111.126 16.415 -5.562 16.076 6.877 19.191 111.800 18.271 114.441 16.211 -2.300 16.008 -2.664 18.698 106.693 18.131 109.659 16.076 6.792 15.341 0.311 18.556 107.274 17.445 104.121 16.008 -1.796 15.056 -7.155 18.342 109.347 17.310 105.795 15.341 1.624 13.249 -1.334 18.201 108.857 17.171 101.832 15.198 13.186 13.094 -13.591 17.378 101.803 16.966 107.620 15.056 -6.003 12.993 0.282 17.241 107.170 16.828 113.181 13.249 0.193 12.836 -4.052 17.035 102.426 16.346 104.478 13.094 -11.810 12.578 5.191 16.897 105.076 16.144 107.729 12.993 1.585 10.036 -3.732 16.415 110.632 16.008 111.134 12.836 -3.517 10.018 -7.816 16.211 110.265 16.007 103.800 12.578 6.139 9.730 -2.066 16.076 104.066 15.465 108.001 12.339 8.475 9.519 -8.827 16.000 106.187 15.271 101.123 12.158 4.991 8.543 0.830 16.008 105.699 15.126 110.742 12.037 7.541 8.404 -8.632 16.006 105.096 14.911 101.797 10.036 -3.141 8.191 -3.565 15.341 99.508 13.145 102.546 10.018 -6.386 8.049 -3.102 15.198 97.841 13.044 98.505 9.730 -0.625 8.005 2.397 15.056 108.299 12.941 98.590 9.519 -9.107 6.616 -0.467 13.468 97.195 12.783 101.317 8.543 1.388 6.469 0.347 13.249 102.348 12.519 107.560 8.404 -8.914 6.249 -4.730 13.094 111.696 12.399 101.513 8.191 -2.653 6.103 -3.381 12.993 97.051 12.217 108.615 8.049 -1.905 5.569 4.125 12.836 105.010 12.098 108.577 8.005 3.503 5.200 -16.551 12.722 96.283 11.980 105.973 8.011 2.422 4.998 -1.086 12.570 97.935 10.645 101.621 6.616 0.050 4.865 2.152 12.578 101.339 9.998 99.157 6.469 0.310 4.723 -6.248 12.339 100.129 10.010 104.463 6.249 -4.915 4.511 2.665 12.158 103.415 10.021 95.615 6.103 -2.844 4.369 -4.198 12.037 98.542 9.930 109.034 5.569 5.513 2.869 5.830 11.868 94.262 9.660 103.818 5.347 2.946 2.651 -1.301 10.372 102.432 8.613 95.984 5.200 -14.680 2.358 4.800 10.036 102.373 8.474 97.708 4.998 -0.034 1.158 -11.093 10.001 98.413 8.262 91.248 4.865 3.576 1.011 -6.905 10.004 107.101 8.120 91.140 4.723 -5.168 0.995 -5.380 10.011 104.878 8.003 94.138 4.511 4.011 1.000 -4.952 10.018 102.138 6.905 101.031 4.369 -3.928 1.004 -9.084 10.022 110.152 6.542 98.641 2.869 7.373 1.006 -8.924 9.730 104.471 6.395 99.629 2.651 0.406 1.007 -8.525 9.519 105.601 6.176 98.170 2.358 6.192 0.842 -0.291 8.543 96.371 5.273 102.571 1.158 -11.093 0.697 -4.990 8.404 100.178 5.126 92.691 1.011 -6.905 0.515 -4.775 8.191 93.624 4.937 99.024 0.995 -5.380 -0.096 -11.235 8.049 95.966 4.794 99.311 1.000 -4.952 -0.001 -8.989 8.005 97.612 4.583 95.643 1.004 -9.084 -0.004 -3.659 8.011 98.642 4.440 102.201 1.006 -8.924 -0.029 -9.208 6.834 94.130 4.297 92.602 1.007 -6.866 -0.369 -10.707 6.616 98.592 2.939 102.398 0.842 1.689 -0.501 -11.190 6.469 99.321 2.796 101.553 0.697 -2.083 -0.501 -1.839 6.249 103.245 2.578 97.647 0.515 -2.645 -0.497 -6.581 6.103 105.574 2.210 100.560 0.501 -2.665 -0.907 -2.599 5.569 97.212 1.305 87.300 -0.096 -9.318 -1.735 -3.844 5.347 99.635 1.085 86.654 -0.001 -6.880 -2.201 -8.749 5.200 108.640 0.994 89.464 -0.004 -1.575 -10.546 2.906 4.998 99.057 0.997 90.620 -0.029 -9.208 -12.045 5.216 4.865 95.882 1.001 90.694 -0.030 -7.886 -12.638 -5.283 4.723 100.856 1.004 91.938 -0.369 -9.389 -12.861 -3.150 4.511 98.260 0.914 88.020 -0.501 -10.241 -13.229 -0.450 4.369 96.388 0.770 95.203 -0.501 -0.249 -13.380 -8.081 2.869 94.580 0.657 94.750 -0.497 -6.148 -14.651 -5.571 2.651 97.252 0.498 90.742 -0.907 -1.478 -15.169 -3.789 2.358 94.697 0.004 93.012 -1.000 -3.536 -15.391 -8.536 1.158 97.466 -0.060 88.765 -1.735 -2.454 -15.537 -6.171 1.011 96.100 -0.005 89.502 -1.950 -3.767 -15.684 -2.606 0.995 95.772 -0.008 93.437 -2.201 -8.749 -15.911 0.488 1.000 95.419 -0.029 85.891 -10.546 4.878 -16.064 -0.680 1.004 101.125 -0.440 92.993 -12.045 4.085 -16.296 -2.320 1.006 96.645 -0.502 85.978 -12.638 -7.080 -16.449 -6.301 1.007 94.509 -0.499 99.729 -12.861 -4.750 -16.760 -1.861 0.842 93.622 -0.494 87.771 -13.229 -1.300 -17.378 1.343 0.697 96.766 -0.837 93.129 -13.380 -7.428 -17.531 -5.241 0.515 93.207 -0.978 93.313 -14.281 -7.324 -17.680 -5.399 0.501 95.558 -0.997 90.950 -14.651 -6.002 -17.908 -6.116 -0.096 97.886 -1.878 92.040 -15.169 -3.637 -18.058 0.390 -0.001 96.115 -2.001 96.314 -15.391 -8.826 -18.284 -5.717 -0.004 94.932 -2.135 88.580 -15.537 -6.742 -18.435 0.090 -0.029 102.424 -2.329 89.740 -15.684 -3.089 -18.587 -2.785 -0.030 100.954 -11.254 97.080 -15.911 -0.500 -18.813 -6.276 -0.369 102.628 -11.753 99.036 -16.064 -0.854 -18.960 -0.483 -0.501 95.787 -11.900 93.271 -16.296 -3.800 -19.269 -4.305 -0.501 99.978 -12.118 100.498 -16.449 -7.526 -19.722 -4.172 -0.497 93.521 -12.413 99.221 -16.760 -3.128 -19.908 -6.749 -0.907 94.714 -12.785 92.479 -17.378 0.285 -20.041 -3.949 -1.000 94.284 -12.937 93.669 -17.531 -6.052 -20.680 -3.160 -1.593 97.140 -13.083 100.368 -17.680 -6.768 -21.089 -6.020 -1.735 94.356 -13.304 95.532 -17.908 -6.893 -21.430 -1.382 -1.950 100.083 -13.456 92.831 -18.058 -1.306 -21.512 -4.555 -2.201 98.344 -14.354 94.562 -18.284 -6.123 -2.378 98.651 -14.725 97.051 -18.435 -0.382 -8.270 98.367 -14.949 90.639 -18.587 -3.228 -8.402 97.726 -15.096 97.999 -18.813 -7.460 -8.604 96.845 -15.242 95.910 -18.960 -0.601 -8.942 97.090 -15.464 89.145 -19.269 -4.616 -9.039 100.217 -15.611 92.104 -19.489 -9.234 -9.351 95.066 -15.834 94.204 -19.722 -4.420 -9.475 92.581 -15.987 93.153 -19.908 -6.646 -9.664 91.546 -16.141 95.641 -20.041 -4.057 -9.792 93.049 -16.372 90.795 -20.232 -6.459 -9.921 92.065 -16.527 90.091 -20.362 -2.758 -10.114 98.123 -16.914 99.516 -20.490 -0.158 -10.240 103.207 -17.070 96.156 -20.680 -3.129 -10.546 92.564 -17.455 99.958 -20.805 -2.484 -11.325 92.616 -17.605 94.990 -20.983 -6.554 -12.045 96.554 -17.833 90.649 -21.089 -5.863 -12.638 99.525 -17.984 92.615 -21.430 -0.828 -12.861 98.340 -18.134 92.821 -21.512 -5.489 -13.229 96.790 -18.358 90.933 -13.380 100.280 -18.512 92.970 -14.281 102.035 -18.738 95.684 -14.501 98.976 -18.886 91.121 -14.651 103.249 -19.036 93.673 -15.169 99.529 -19.345 95.518 -15.391 97.774 -19.664 89.733 -15.537 98.763 -19.844 94.352 -15.684 97.206 -19.975 96.475 -15.911 93.621 -20.105 92.049 -16.064 96.464 -20.298 95.534 -16.296 94.381 -20.426 96.621 -16.449 97.423 -20.615 97.939 -16.760 102.730 -20.745 97.033 -17.148 99.280 -20.864 99.607 -17.378 99.674 -21.041 95.291 -17.531 101.110 -21.128 94.336 -17.680 97.230 -21.471 96.121 -17.908 99.471 -21.552 89.188 -18.058 94.049 -18.284 96.864 -18.435 93.327 -18.587 98.875 -18.813 98.466 -18.960 94.240 -19.269 100.140 -19.489 98.862 -19.722 98.715 -19.908 103.344 -20.041 95.941 -20.232 102.131 -20.362 99.361 -20.490 98.094 -20.680 100.168 -20.805 102.145 -20.983 101.975 -21.089 100.210 -21.171 98.774 -21.430 96.924 -21.512 94.368 -21.920 97.378