These data were produced by NOAA and are not subject to copyright protection in the United States. NOAA waives any potential copyright and related rights in these data worldwide through the Creative Commons Zero 1.0 Universal Public Domain Dedication (CC0 1.0)
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4. WARNINGS
Every effort is made to produce the most accurate and precise
measurements possible. However, we reserve the right to make
corrections to the data based on recalibration of standard gases
or for other reasons deemed scientifically justified.
We are not responsible for results and conclusions based on use
of these data without regard to this warning.
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5. UPDATE NOTES
+++++++++++++++++++++++++++++++
Project-specific notes:
2024-02-08
Mauna Loa:
Because of power loss to the observatory due to the eruption of the Mauna Loa
volcano in Novermber 2022, no data are available for January to June 2023. Partial power
was restored using solar power and backup batteries in July 2023, and CH4 measurements resumed
on July 5, 2023.
2023-07-27
Barrow:
Small revisions to the data from 2013 to 2022 were made based on improved assignments
to the standard gases and improved determination of the analyzer response.
These revisions were less than 0.5 ppb.
Mauna Loa:
Small revisions to the data from April 2019 to 2022 were made based on improved assignments
to the standard gases and improved determination of the analyzer response.
These revisions were less than 0.5 ppb. Due to the eruption of the Mauna Loa Volcano,
measurements from Mauna Loa Observatory were suspended as of Nov. 29, so there is no
data for the end of November 2022 and all of December 2022.
Mauna Kea:
Measurements of CH4 began at Mauna Kea, Hawaii, approximately 21 miles north
of Mauna loa, in December 2022, to replace the measurements that were suspended at
Mauna Loa.
2021-08-31
Barrow: Transitioned to new intake lines on a new tower. Intake height
changed from 16.46 m to 35.05 m.
2020-08-19
For measurements made with laser-based spectrometers (instrument =
LGR* and PC*), value_std_dev can now be defined when nvalue (number
of measurements) = 1. See Introduction for details.
2020-03-16
Measurements of CH4 at Mauna Loa, Hawaii were switched from
a GC to a CRDS in April, 2019. Calibration strategy and
measurement frequency changed.
2018-03-16
Measurement uncertainty added to all CH4 hourly averages.
The column/variable previously labeled value_unc is now
labeled value_std_dev and contains the hourly average
standard deviation. See Section 6 (Introduction) for
measurement uncertainty calculation.
The daily and monthly average standard deviations
(formerly value_unc) are now labled value_std_dev.
2016-01-20
All CH4 measurements are reported on the NOAA X2004A scale.
https://gml.noaa.gov/ccl/ch4_scale.html
2014-08-12
Barrow in situ measurements through 2013 are now available.
2014-07-29
Barrow in situ measurements were restarted in April 2013. The 2013 data
are not included in this update due to new instrumentation. 2013 data
will be available sometime in the next few months.
2013-03-29
The CH4 in situ measurements at Barrow were suspended in June 2012.
They will resume in 2013.
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6. INTRODUCTION
NOAA GML began quasi-continuous measurements of atmospheric CH4
at Barrow, Alaska (BRW) in January, 1986 and at Mauna Loa, Hawaii
(MLO) in April, 1987. Since the start of these measurements,
our methods have evolved as described below.
Analytical:
Our first CH4 measurement systems at BRW and MLO were based on gas
chromatography (GC) with flame ionization detection (FID) (for
details, see Dlugokencky et al., 1995). At Barrow, from January
1986 through April 1996, 2 to 3 individual measurements were made
each hour. From May 1996 through May 2012, 4 measurements were made
each hour. At Mauna Loa, from April 1987 through November 1995, 2
to 3 individual measurements were made each hour, and from December
1995 to April 2019, 4 atmospheric measurements were made each hour.
Our next-generation analytical systems use laser-based spectrometers
to measure CH4. We began using a new system (off-axis, integrated
cavity output spectroscopy, ICOS) at BRW in April 2013. There is a gap
in the CH4 measurements at BRW from June, 2012 until April, 2013. Data
are saved as 10-second averages, which are averaged into "5-minute
averages". Our measurement sequence starts with 210 seconds of
flushing, so only the last 90 seconds (9 10-second averages) are used
to calculate each 5-minute average. At MLO, we switched to a laser-
based, cavity ringdown spectrometer (CRDS) in April 2019, and now use
a similar data processing scheme to BRW.
Calibration:
GC/FID systems were calibrated with a single-point calibration; each
aliquot of ambient air was bracketed by aliquots of standard gas, and
CH4 in each air sample was calculated based on the ratio of the sample
chromatographic peak response to the average response of the
bracketing standards, and the assigned value for the standard
cylinder.
For laser-based spectrometers, the analyzer response is calibrated
with a suite of standards every two weeks relative to a reference
cylinder, and the reference cylinder is measured hourly to track and
correct short term analyzer drift. As a quality assurance step, a
well-calibrated "target" cylinder is measured up to twice per day.
NOAA methane measurements are reported on the gravimetrically-prepared
NOAA X2004A CH4 standard scale (see Dlugokencky et al., 2005;
https://gml.noaa.gov/ccl/ch4_scale.html).
Quality control:
All measurements by GC were first edited using a rule-based
editing algorithm (Masarie et al., 1991) to exclude measurements
obtained when the analytical instrument was not working optimally.
New algorithms were developed to edit data from the off-axis ICOS
instrument at BRW since April, 2013 and the CRDS at MLO since
April, 2019.
Hourly averages:
For GC/FID systems, hourly averages were calculated from all valid
measurements within an hour and reported in our data files with the
number of measurements (nvalue) and standard deviation (value_std_dev).
For n=1, value_std_dev cannot be calculated.
For spectrometer systems, 5-minute averages are used to calculate
hourly averages, but value_std_dev includes variability in the 5-min
averages, so it is greater than the normal sample SD of the 5-min
averages that go into the hourly mean, and when nvalue=1 (i.e., one
5-min average in the hourly mean), value_std_dev is still calculated
and reported.
Selection for background:
Valid hourly averaged data are selected to distinguish samples of
regionally representative air (background) from samples influenced
by local sources and sinks (non-background). Background hourly
data are identified with a "..." selection flag. A ".C." flag is
assigned to data identified as non-background. The criteria for
determining background conditions are site specific. The background
criteria for Barrow are when the wind is from the clean air sector
(020-110 degrees) and wind speed is greater than 1 m/s for at
least one hour prior to inclusion. The background criteria
for Mauna Loa are during predominatly "downslope" meteorological
conditions as indicated by local time of day, 0000-0659.
See Dlugokencky et al. [1995] for details.
Uncertainties:
Measurement uncertainties (value_unc) are calculated for each measurement
(individual aliquot on GC and 5-minute average on optical spectrometer)
based on analytical repeatability and reproducibility, and our ability to
propagate the WMO CH4 mole fraction standard scale. For GCs, analytical
repeatability is based on the stability of standard or reference aliquots
averaged over the period a particular instrument was used. It varies with
analytical instrument from 5.5 to 0.9 ppb. For laser-based spectrometers,
it is based on the standard deviations of the bracketing measurements of
reference gas. Reproducibility is based on a comparison of near-
simultaneous flask-air samples measured independently in Boulder and
quasi-continuous hourly averaged measurements at MLO and BRW
observatories. It is assessed from the median difference, and it ranges
from 0.1 to 0.9 ppb. The scale propagation term is based on the
uncertainty we assign to standards, 0.5 ppb. All terms are given as 68%
confidence intervals. Although we still list "value_std_dev" of hourly
averages (standard deviation of values that go into an hourly average as
described above, which includes natural variability and measurement
uncertainty), we now list measurement uncertainty as a separate term.
For the hourly average uncertainty, repeatability is divided by sqrt n,
where "n" is the number of observations used in the calculation.
Reproducibility and scale propagation terms are applied once. Total
uncertainty is calculated by adding the individual terms in quadrature
(square root of the sum of the squares). Methane hourly average values
outside the range of standards are assigned a default uncertainity
(-999.99).
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7. DATA - GENERAL COMMENTS
7.1 DATA - SAMPLING LOCATIONS
For a summary of sampling locations, please visit
https://gml.noaa.gov/dv/site/index.php?program=ccgg.
Note: Data for all species may not be available for all sites listed
in the table.
To view near real-time data, manipulate and compare data, and create
custom graphs, please visit
https://gml.noaa.gov/dv/iadv/.
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7.2 DATA - FILE NAME DESCRIPTION
Encoded into each file name are the parameter (trace gas identifier); sampling
site; sampling project; laboratory ID number; measurement group (optional); and optional
qualifiers that further define the file contents.
All file names use the following naming scheme:
1 2 3 4 5
[parameter]_[site]_[project]_[lab ID number]_[optional measurement group]_[optional
6 7
qualifiers].[file type]
1. [parameter]
Identifies the measured parameter or trace gas species.
(ex)
co2 Carbon dioxide
ch4 Methane
co2c13 d13C (co2)
merge more than one parameter
2. [site]
Identifies the sampling site code.
(ex)
brw
pocn30
car
amt
3. [project]
Identifies sampling platform and strategy.
(ex)
surface-flask
surface-pfp
surface-insitu
aircraft-pfp
aircraft-insitu
tower-insitu
4. [lab ID number]
A numeric field that identifies the sampling laboratory (1,2,3, ...).
NOAA GML is lab number 1 (see https://gml.noaa.gov/ccgg/obspack/labinfo.html).
5. [optional measurement group]
Identifies the group within the NOAA GML or the Institute of Arctic and Alpine
Research (INSTAAR) at the University of Colorado Boulder that made the
measurement.
It is possible to have multiple different groups measuring some of the same
trace gas species in our discrete samples.
Measurement groups within NOAA and INSTAAR are
ccgg: NOAA Carbon Cycle Greenhouse Gases group (CCGG)
hats: NOAA Halocarbons and other Atmospheric Trace Species group (HATS)
arl: INSTAAR Atmospheric Research Laboratory (ARL)
sil: INSTAAR Stable Isotope Laboratory (SIL)
curl: INSTAAR Laboratory for Radiocarbon Preparation and Research (CURL)
6. [optional qualifiers]
Optional qualifier(s) may indicate data subsetting or averaging.
Multiple qualifiers are delimited by an underscore (_). A more detailed
description of the file contents is included within each data file.
(ex)
event All measurement results for all collected samples (discrete (flask) data only).
month Computed monthly averages all collected samples (discrete (flask) data only).
hour_#### Computed hourly averages for the specified 4-digit year (quasi-continuous data only)
HourlyData Computed hourly averages for entire record (quasi-continuous data only)
DailyData Computed daily averages for entire record (quasi-continuous data only)
MonthlyData Computed monthly averages for entire record (quasi-continuous data only)
7. [file type]
File format (netCDF, ASCII text).
(ex)
txt ASCII text file
nc netCDF4 file
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7.3 DATA - FILE TYPE
We now provide some NOAA Global Monitoring Laboratory measurements
in two unique file formats; netCDF and ASCII text.
The Network Common Data Form (NetCDF) is a self-describing, machine-independent
data format that supports creation, access, and sharing of array-oriented
scientific data. To learn more about netCDF and how to read netCDF
files, please visit http://www.unidata.ucar.edu.
The ASCII text (technically UTF-8 encoded) file is derived directly from the
netCDF file. The text file is also self-describing and can be viewed using
any ASCII or UTF-8 capable text editor. "Self-describing" means the file
includes enough information about the included data (called metadata)
that no additional file is required to understand the structure of the data
and how to read and use the data. Note that some non-ASCII characters (accents,
international character sets) may be present in various names and contact
information. These may require a UTF-8 capable text editor to view properly.
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7.4 DATA - CONTENT
For each observatory we provide hourly, daily, and monthly
averaged files. Daily averages are derived directly from the hourly
data. Monthly averages are calculated from values extracted at one-day
intervals from a smooth curve (Thoning et al., 1989) fitted to the
daily averages. Higher resolution data (sub-hourly) are available
upon request.
All (ASCII text and netCDF) files are located in
"https://gml.noaa.gov/aftp/data/trace_gases/ch4/in-situ/surface/".
Files are named as follows (see Section 7.2 for details):
ch4_[site]_surface-insitu_1_ccgg_HourlyData.[file type]
ch4_[site]_surface-insitu_1_ccgg_DailyData.[file type]
ch4_[site]_surface-insitu_1_ccgg_MonthlyData.[filetype]
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7.5 QC FLAGS
NOAA GML uses a 3-column quality control flag where each column
is defined as follows:
column 1 REJECTION flag. An alphanumeric other
than a period (.) in the FIRST column indicates
a sample with obvious problems during collection
or analysis. This measurement should not be interpreted.
column 2 SELECTION flag. An alphanumeric other than a
period (.) in the SECOND column indicates a sample
that is likely valid but does not meet selection
criteria determined by the goals of a particular
investigation.
column 3 INFORMATION flag. An alphanumeric other than a period (.)
in the THIRD column provides additional information
about the collection or analysis of the sample.
WARNING: A "P" in the 3rd column of the QC flag indicates
the measurement result is preliminary and has not yet been
carefully examined by the PI. The "P" flag is removed once
the quality of the measurement has been assessed.
SUMMARY OF SELECTION FLAGS
... - no flag applied
*.. - Unable to compute a mole fraction or average
.C. - data are non-background
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8. DATA RETRIEVAL
Users may transfer individual files or a single zipped file:
https://gml.noaa.gov/aftp/data/trace_gases/ch4/in-situ/surface/
Zipped files contain the README file and either netCDF files or ASCII text
files depending on the zipped file name.
(ex) ch4_mlo_surface-insitu_1_ASCIItext.zip
(ex) ch4_mlo_surface-insitu_1_netCDF.zip
Zipped files can be expanded using standard operating system utilities
by double clicking downloaded file.
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9. REFERENCES
Dlugokencky, E.J., R.C. Myers, P.M. Lang, K.A. Masarie, A.M. Crotwell,
K.W. Thoning, B.D. Hall, J.W. Elkins, and L.P. Steele, 2005, Conversion
of NOAA CMDL atmospheric dry air methane mole fractions to a
gravimetrically-prepared standard scale, J. Geophys. Res., 110, D18306,
doi : 10.1029/2005JD006035.
Dlugokencky, E.J., L.P. Steele, P.M. Lang, and K.A. Masarie,
Atmospheric methane at Mauna Loa and Barrow observatories:
presentation and analysis of in situ measurements, J. Geophys. Res.,
100, 23,103-23,113, 1995.
Masarie, K.A., L.P. Steele, and P.M. Lang, A rule-based expert system
for evaluating the quality of long-term, in situ, gas chromatographic
measurements of atmospheric methane, NOAA Tech. Memo. ERL CMDL-3,
NOAA Environ. Res. Lab., Boulder, Colorado, 1991.
Thoning, K.W., P.P. Tans, and W.D. Komhyr, Atmospheric carbon dioxide
at Mauna Loa Observatory 2. Analysis of the NOAA GMCC data, 1974-1985,
J. Geophys. Res., 94, 8549-8565, 1989.
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