*************************************************************************** ATMOSPHERIC TRACE GAS MIXING/ISOTOPE RATIOS derived from samples collected using the NOAA CMDL Portable Flask Packages (PFP) Measurements made at: 1. NOAA Earth System Research Laboratory (CMDL): Dec. 2000 - Aug. 2003 2. Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo: April, 2004 - present Contributed by: John B. Miller Pieter P. Tans NOAA/ESRL 325 Broadway Boulder, CO 80305 john.b.miller@noaa.gov Luciana V. Gatti lvgatt@ipen.br *********************************NOTICE************************************ When using the PFP merged data in a publication or presentation, please acknowledge the National Oceanic and Atmospheric Administration (NOAA), Earth System Research Laboratory (ESRL), Carbon Cycle Greenhouse Gases Group and IPEN. The principal investigators would appreciate receiving manuscripts that use the data to ensure that the quality and limitations of the data are accurately represented. Feedback from users may also help us to improve the quality of the data and the locations of the sampling sites. Comments regarding the README files and the data files are encouraged. Please send comments to the e-mail address given above. ************************************WARNING******************************** NOAA ESRL has attempted to provide the most precise measurements possible. We reserve the right to make adjustments to the data when made necessary by adjustments to calibration scales. *************************************************************************** Aircraft merged files contain one line for each Portable Flask Package (PFP) sample. Lines may read using the following FORTRAN format statement: A3,1X,A16,1X,A8,1X,A1,3(1X,F8.2),1X,2(F7.1,1X),F6.1,1X,I8,8(1X,F9.3,1X,A3) The fields in a single line are defined as follows: sta yyyy mm dd hh mm xxxxx-xx c ddd.dd dddd.dd ddddd.dd dddd.d dddd.d dddd.d xxxxxx dddd.ddd fff dddd.ddd fff dddd.ddd fff dddd.ddd fff dddd.ddd fff dddd.ddd fff dddd.ddd fff dddd.ddd fff where: sta = the three-letter station code. yyyy mm dd = the UTC year, month, and day (four digit year, two digit month and day) when the sample was collected hh mm = the UTC time (hour, minutes; two digits each) of sample collection xxxxx-xx = the flask sample I.D. number. This field can contain up to eight characters but may contain fewer. This field may contain letters as well as numbers. c = a one letter code that identifies the sample collection method. ddd.dd = Latitude during collection in decimal degrees dddd.dd = Longitude during collection in decimal degrees dddd.dd = Altitude during collection in meters above sea level dddd.d = air temperature in degree C (default = -40.0) dddd.d = air pressure in millibars (default = -99.0) dddd.d = percent relative humidity (default = 11.3) xxxxxxxx = internal CMDL event number; unique for each sampling event ddddd.ddd fff = CO2 mixing ratio in ppm. Missing values are denoted by -999.99. "fff" is a three-character flag indicating the results of our data selection process. An alphanumeric other than a period (.) in the FIRST column indicates samples with obvious problems during sample collection or analysis. An alphanumeric other than a period (.) in the SECOND column indicates samples which are believed to be non-background. An alphanumeric other than a period (.) in the THIRD column is a sample qualifier that is not presently used. ddddd.ddd fff = CH4 mixing ratio in ppb and flag. Missing values are denoted by -999.99. ddddd.ddd fff = CO mixing ratio in ppb and flag. Missing values are denoted by -999.99. ddddd.ddd fff = H2 mixing ratio in ppb and flag. Missing values are denoted by -999.99. ddddd.ddd fff = N2O mixing ratio in ppb and flag. Missing values are denoted by -999.99. ddddd.ddd fff = SF6 mixing ratio in ppt and flag. Missing values are denoted by -999.99. dddd.ddd fff = d13C (CO2) isotope ratio in per mil and flag. Missing values are denoted by -999.999. dddd.ddd fff = d18O (CO2) isotope ratio in per mil and flag. Missing values are denoted by -999.999. !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! !!!!NOTE!!: NO D18O CO2 DATA ARE RELIABLE FROM OUR BRAZILIAN!!!!!! !!!!SITES DUE TO HUMIDITY CONTAMINATION.!!!!!!!!!!!!!!!!!!!!!!!!!! !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! ***************************************************************************