by Ralph Keeling
Measurements
of atmospheric O2/N2 ratio and CO2
concentration are presented over the period 1989 to present from the Scripps
Institution of Oceanography global flask sampling network. The data are used to
make estimates of land and ocean sinks over various time scales. The oceanic
and land biotic sinks are estimated to be 1.9±0.6 (ocean) and 1.2±0.8 Pg C/yr
(land) over the period Jan. 1990-Jan. 2000 and 2.2±0.5 (ocean) and 0.5±0.7 Pg
C/yr (land) over the period Jan. 1993-Jan. 2003. These estimates make allowance
for oceanic O2 and N2 outgassing based on observed
changes in ocean heat content and estimates of the relative outgassing per unit
warming. The recent ocean sink is consistent, to within the uncertainties, with
estimates of the accumulation of anthropogenic CO2 in the ocean
since 1800, assuming the oceanic sink varied over time as predicted by a
box-diffusion model. The possibility that the ocean sink is being reduced
slightly by climate feedbacks, as predicted by some models, is not ruled out,
however.
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