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Re: An Empirical Estimate of the Southern Ocean Air-Sea CO2 Flux
(Score 2, Informative)
by Ben.McNeil on Tuesday, September 27 @ 12:14:31 MDT
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Thanks for the comment Frank and it seems to be an on-going debate as to which carb constants to use. Yes, the method we use is vulnerable to which constants you use. It seems to me from my experience that there isn't one set of carb constants which are optimal over the entire ocean - and there are regionally dependencies. The uncertainties in DIC and ALK were included in the analysis and yes further south the uncertainty in the pco2 is +/-20ppm but that varies significantly over the Southern Ocean down to +/-10ppm in the SAZ.The best way to determine the optimal carb constants in the Southern ocean is to have 3 or more measurements on the same bottle (ie DIC, ALK, pCO2, ph) - and what Sabine/Feely tell me that NOAA cruises nowadays measure 3-4 carbon parameters per bottle and we will be able to really constrain the 'optimal' constants to use in the future. When this happens, the uncertainty in this methodology will decrease dramatically. Your work is extremely valluable in this context and I would definitely like to talk to you more about this.
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The 7th International CO
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September 25th - 30th
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